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The Louis Stokes Alliances for Minority Partnerships (LSAMP) program funded through the National Science Foundation (NSF) brings together partner institutions of higher education to promote student success. Teams of regional partners build programs to support their students in academic, research, and career achievement. Developing programs that meet the needs of a cooperative alliance composed of institutions of varying sizes and types requires logistical planning and flexibility. This paper presents a summary of factors that were considered as a new alliance, Southern and Central Illinois LSAMP (SCI-LSAMP), established through a multi-year planning process. The goal of the alliance was to create an integrated LSAMP program that facilitates students' growth within their home institutions and builds connections across the alliance’s partner institutions. Factors considered to build a cohesive program include existing institutional programming, research infrastructure, administrator and faculty workflow, schedules and needs, and conversations with established LSAMP programs. This paper aims to serve as a roadmap for new alliances to consider as they plan for multi-institution collaborations. 

Abstract Bond distance is a common structural metric used to assess changes in metal–ligand bonds, but it is not clear how sensitive changes in bond distances are with respect to changes in metal–ligand covalency. Here we report ligand K‐edge XAS studies on Ni and Pd complexes containing different phosphorus(III) ligands. Despite the large number of electronic and structural permutations, P K‐edge pre‐edge peak intensities reveal a remarkable correlation that spectroscopically quantifies the linear interdependence of covalent M−P σ bonding and bond distance. Cl K‐edge studies conducted on many of the same Ni and Pd compounds revealed a poor correlation between M−Cl bond distance and covalency, but a strong correlation was established by analyzing Cl K‐edge data for Ti complexes with a wider range of Ti−Cl bond distances. Together these results establish a quantitative framework to begin making more accurate assessments of metal–ligand covalency using bond distances from readily‐available crystallographic data.